A trivalent 4f complex with two bis-silylamide ligands displaying slow magnetic relaxation

116 Chemical sciences

The authors acknowledge the University of Ottawa, the Natural Sciences and Engineering Research Council of Canada and the Canadian Foundation for Innovation for funding and supporting this work. A.M. acknowledges funding provided by the Academy of Finland (grant number 332294) and the University of Oulu (Kvantum Institute). Computational resources were provided by CSC-IT Center for Science in Finland and the Finnish Grid and Cloud Infrastructure (persistent identifier urn:nbn:fi:research-infras-2016072533).

Crystallographic data for the structures reported in this article have been deposited at the Cambridge Crystallographic Data Centre, under deposition numbers CCDC 2222783 (1 at 200 K), 2222786 (2 at 200 K) and 2222787 (2 at 90 K). Copies of the data can be obtained free of charge via https://www.ccdc.cam.ac.uk/structures/. All other data generated or analysed are made available as Source Data or in the Supplementary Information. Source data are provided with this paper.